Stereoselective Synthesis of -Butyrolactones Subunit of Polycavernoside A

被引：5

作者：

Kadari, Sudhakar ^{[1
]}

Yerrabelly, Hemasri ^{[1
]}

Gogula, Thirupathi ^{[1
]}

Erukala, Yadaiah Goud ^{[1
]}

Yerrabelly, Jayaprakash Rao ^{[1
]}

Begari, Prem Kumar ^{[1
]}

机构：

[1] Osmania Univ, Dept Chem, Hyderabad 500007, Telangana, India

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2018年 / 55卷 / 08期

关键词：

TOXIN POLYCAVERNOSIDE; RED ALGA; ABSOLUTE-CONFIGURATION; STRUCTURE REVISION; GRACILARIA-EDULIS; ONE-POT; DERIVATIVES; RUGULACTONE; EFFICIENT; ALCOHOLS;

D O I：

10.1002/jhet.3240

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and versatile linear synthesis of -butyrolactone subunit of polycavernolide A has been reported in 14.2% overall yield with 10 linear steps by employing Sharpless asymmetric epoxidation, ring-closing metathesis, and diastereoface selective hydrogenation.

引用

页码：1986 / 1990

页数：5

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