Stereoselective Synthesis of -Butyrolactones Subunit of Polycavernoside A

被引:5
|
作者
Kadari, Sudhakar [1 ]
Yerrabelly, Hemasri [1 ]
Gogula, Thirupathi [1 ]
Erukala, Yadaiah Goud [1 ]
Yerrabelly, Jayaprakash Rao [1 ]
Begari, Prem Kumar [1 ]
机构
[1] Osmania Univ, Dept Chem, Hyderabad 500007, Telangana, India
关键词
TOXIN POLYCAVERNOSIDE; RED ALGA; ABSOLUTE-CONFIGURATION; STRUCTURE REVISION; GRACILARIA-EDULIS; ONE-POT; DERIVATIVES; RUGULACTONE; EFFICIENT; ALCOHOLS;
D O I
10.1002/jhet.3240
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient and versatile linear synthesis of -butyrolactone subunit of polycavernolide A has been reported in 14.2% overall yield with 10 linear steps by employing Sharpless asymmetric epoxidation, ring-closing metathesis, and diastereoface selective hydrogenation.
引用
收藏
页码:1986 / 1990
页数:5
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