Low temperature phase of a new type metal-insulator transition system

被引：8

作者：

Ota, A ^{[1
]}

Yamochi, H ^{[1
]}

Saito, G ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Div Chem, Kyoto, Japan

来源：

SYNTHETIC METALS | 2003年 / 135卷 / 1-3期

关键词：

metal-insulator phase transition; order-disorder phase transition; X-ray diffraction; organic conductors based on radical cation;

D O I：

10.1016/S0379-6779(02)00758-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

(Ethylenedioxytetrathiafulvalene)(2)PF6 shows a first order Metal-Insulator transition at around 280 K, of which mechanism implies the cooperative features of Peierls, charge ordering, and anion ordering transitions with the large molecular deformation. The anisotoropic thermal contraction of the crystal structure is described along with the freezing of the anion disorder observed at 110 K.

引用

页码：643 / 644

页数：2

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