The crystal and molecular structure of a new macrocyclic ligand, (H6BDBPH)Br6•4H2O

被引：0
|
作者：
Shangguan, GQ [1 ]
Martell, AE
Zhang, ZR
Reibenspies, J
机构：
[1] Jining Med Coll, Dept Chem, Jining 272013, Peoples R China
[2] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2000年 / 19卷 / 05期
关键词：
macrocyclic ligand; synthesis; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hexahydro-bromide salt of a new 24-membered hexaaza diphenol macrocyclic ligand, (H6BDBPH) Br-6. 4H(2)O (C26H56N6O6Br6, M-r. = 1028.23) crystallizes in the monoclinic system, space group P2(1)/c, with cell parameters: a = 14.441 (5), b = 11.482(4), c = 12.090(6)Angstrom, beta = 96.92 degrees, V = 1990 (1) Angstrom(3), Z = 2, D-c 1.716 g/cm(3); F(000) = 1024. MoK alpha radiation, lambda = 0.71013 Angstrom), R = 0.0643 and omega R = 0.1356 for 3507 independent reflections with I > 2 sigma(I). The macrocyclic ligand adapts chair form, and the crystallographic inversion center is located in the macrocyclic cavity, and the six bromide ions and four water molecules are situated symmetrically outside the macrocyclic cavity.
引用
收藏
页码：334 / 337
页数：4
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