The energies, fine structures, widths, and radiative rates of core-excited states of a Li isoelectronic sequence (Z=4-14) are calculated using the saddle point and saddle-point complex-rotation methods. A restricted variational method is used to extrapolate a better nonrelativistic energy. Relativistic effects are included using first-order perturbation theory. The charged effects of the Li isoelectronic sequence are discussed. These results are compared with experimental and theoretical data in the literature.
机构:
Nancy Univ, Fac Sci & Tech, Equipe Chim & Biochim Theor,FR CNRS 2843, UMR 7565 CNRS UHP,Inst Jean Barriol, F-54506 Vandoeuvre Les Nancy, FranceNancy Univ, Fac Sci & Tech, Equipe Chim & Biochim Theor,FR CNRS 2843, UMR 7565 CNRS UHP,Inst Jean Barriol, F-54506 Vandoeuvre Les Nancy, France
Loos, Pierre-Francois
Assfeld, Xavier
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Nancy Univ, Fac Sci & Tech, Equipe Chim & Biochim Theor,FR CNRS 2843, UMR 7565 CNRS UHP,Inst Jean Barriol, F-54506 Vandoeuvre Les Nancy, FranceNancy Univ, Fac Sci & Tech, Equipe Chim & Biochim Theor,FR CNRS 2843, UMR 7565 CNRS UHP,Inst Jean Barriol, F-54506 Vandoeuvre Les Nancy, France