Tailoring the Polymer-Derived Carbon Encapsulated Silicon Nanoparticles for High-Performance Lithium-Ion Battery Anodes

被引:44
|
作者
Ma, Qiang [1 ]
Xie, Hongwei [1 ]
Qu, Jiakang [1 ]
Zhao, Zhuqing [1 ]
Zhang, Beilei [1 ]
Song, Qiushi [1 ]
Xing, Pengfei [1 ]
Yin, Huayi [1 ,2 ]
机构
[1] Northeastern Univ, Sch Met, Shenyang 110819, Peoples R China
[2] Northeastern Univ, Minist Educ, Key Lab Data Analyt & Optimizat Smart Ind, Shenyang 110819, Peoples R China
关键词
Si@polymer; Si@C; anode; lithium-ion battery; melamine resin; carbonization; SI-C NANOCOMPOSITES; POROUS SILICON; AT-CARBON; HIGH-CAPACITY; DOPED GRAPHENE; ACTIVE-SITES; COMPOSITE; NITROGEN; HETEROSTRUCTURES; ELECTRODES;
D O I
10.1021/acsaem.9b01463
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure, dopants, and surface area of carbon determine the performance of the core-shell structured silicon and carbon composite (Si@C) anode for Li-ion batteries (LIBs). Herein, we report the synthesis of Si@C composite from poly(vinyl alcohol) (PVA)/melamine resin (MR) dual layer polymer derived carbon encapsulated Si nanoparticles using a polymerization-carbonization approach. The dual polymer layer derived carbon coating has adequate void spaces and dopants, possesses a disordered structure, and seals the Si core sufficiently. Hence, the obtained Si@C-MR anode delivers a superior specific capacity of 1279.3 mA h/g at a current density of 2 A/g and with a retention rate of 88.9% after 500 cycles. A full cell with a Li(Ni0.6Co0.2Mn0.2)O-2 cathode and a prelithiated Si@C-MR anode exhibits a high energy density above 518 Wh/kg and capacity retention of 90.1% after 100 cycles. In parallel, the other three polymer-derived Si@C composites were prepared to study the effect of carbon on the performance of the composite anodes. Overall, constructing a dual-polymer layer holds the promise for rationally designing Si@C anodes for high-performance LIBs through the polymerization-carbonization approach.
引用
收藏
页码:268 / 278
页数:21
相关论文
共 50 条
  • [21] Cellulose-derived carbon aerogel from rice straw for high-performance lithium-ion battery anodes
    Pham, Co D.
    Tran, Khoi D.
    Truong, Thanh M.
    Le, Phung K.
    BIOMASS CONVERSION AND BIOREFINERY, 2024, 15 (3) : 4407 - 4415
  • [22] Interpenetrated Gel Polymer Binder for High-Performance Silicon Anodes in Lithium-ion Batteries
    Song, Jiangxuan
    Zhou, Mingjiong
    Yi, Ran
    Xu, Terrence
    Gordin, Mikhail L.
    Tang, Duihai
    Yu, Zhaoxin
    Regula, Michael
    Wang, Donghai
    ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (37) : 5904 - 5910
  • [23] Tailoring nanoscale primary silicon in laser powder b e d fusion for high-performance lithium-ion battery anodes
    Cao, Li
    Zheng, Min
    Dong, Guochen
    Xu, Jiejie
    Xiao, Rongshi
    Huang, Ting
    JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2025, 211 : 278 - 287
  • [24] Nanostructured Silicon Anodes for High-Performance Lithium-Ion Batteries
    Rahman, Md. Arafat
    Song, Guangsheng
    Bhatt, Anand I.
    Wong, Yat Choy
    Wen, Cuie
    ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (05) : 647 - 678
  • [25] Boron-doped three-dimensional porous carbon framework/carbon shell encapsulated silicon composites for high-performance lithium-ion battery anodes
    Zhao, Junkai
    Wang, Bo
    Zhan, Ziheng
    Hu, Meiyang
    Cai, Feipeng
    Swierczek, Konrad
    Yang, Kaimeng
    Ren, Juanna
    Guo, Zhanhu
    Wang, Zhaolong
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2024, 664 : 790 - 800
  • [26] Carbon Encapsulated Silicon Nanoparticles as Anodes for Lithium Ion Batteries
    Livan, P.
    Miser, B.
    Altinok, S.
    Eyovge, C.
    Aydinol, M. K.
    Ozturk, T.
    SELECTED PROCEEDINGS FROM THE 231ST ECS MEETING, 2017, 77 (11): : 373 - 382
  • [27] Compressively Stressed Silicon Nanoclusters as an Antifracture Mechanism for High-Performance Lithium-Ion Battery Anodes
    Salah, Mohammed
    Hall, Colin
    de Eulate, Eva Alvarez
    Murphy, Peter
    Francis, Candice
    Kerr, Robert
    Pathirana, Thushan
    Fabretto, Manrico
    ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (35) : 39195 - 39204
  • [28] MOF-derived MnO/C composites as high-performance lithium-ion battery anodes
    Zhu, Jiping
    Zuo, Xiuxiu
    Chen, Xiang
    Ding, Yuan
    SYNTHETIC METALS, 2021, 280
  • [29] Hybrid Cellular Nanosheets for High-Performance Lithium-Ion Battery Anodes
    Yu, Seung-Ho
    Lee, Dong Jun
    Park, Mihyun
    Kwon, Soon Gu
    Lee, Hyeon Seok
    Jin, Aihua
    Lee, Kug-Seung
    Lee, Ji Eun
    Oh, Myoung Hwan
    Kang, Kisuk
    Sung, Yung-Eun
    Hyeon, Taeghwan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (37) : 11954 - 11961
  • [30] Novel design and synthesis of carbon-coated porous silicon particles as high-performance lithium-ion battery anodes
    Zhao, Tianting
    Zhu, Delun
    Li, Wenrong
    Li, Aijun
    Zhang, Jiujun
    JOURNAL OF POWER SOURCES, 2019, 439