1,2-Diphenyl-2-(m-tolylamino)ethanone

被引:0
|
作者
Mendoza Merono, Rafael [1 ]
Napoles Esculary, Felix [2 ]
Menendez Taboada, Laura [1 ]
Garcia-Granda, Santiago [1 ]
机构
[1] Univ Oviedo, Fac Quim, Dept Quim Fis & Analit, E-33006 Oviedo, Spain
[2] Univ Oriente, Fac Ciencias Nat, Dept Quim, Santiago De Cuba, Cuba
关键词
D O I
10.1107/S1600536810013371
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C(21)H(19)NO, belongs to the family of alpha-aminoketones. The structure contains three benzene rings, two of which [the phenyl ring in the 1-position (B) and the methylaniline ring (A)] are nearly coplanar [dihedral angle = 5.4 (1)degrees], whereas the phenyl ring in the 2-position (C) is nearly normal to them [dihedral angles = 81.8 (1) and 87.0 (1)degrees for A/C and B/C, respectively]. The conformation of the N-H bond is syn to the C=O bond, favouring the formation of a centrosymmetric dimer of molecules in the crystal structure. The molecular packing is consolidated by this N-H center dot center dot center dot O hydrogen-bonding network.
引用
收藏
页码:O1107 / U379
页数:10
相关论文
共 50 条
  • [41] STUDIES IN STEREOCHEMISTRY .22. REARRANGEMENT OF THE 1,1-DIPHENYL-2-PROPYL INTO THE 1,2-DIPHENYL-1-PROPYL SYSTEM
    CRAM, DJ
    ELHAFEZ, FAA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (01) : 28 - 33
  • [42] 1-(1,5-Diphenyl-4-phenylsulfonyl-1H-pyrazol-3-yl)ethanone
    Fun, Hoong-Kun
    Quah, Ching Kheng
    Abdel-Aziz, Hatem A.
    Ghabbour, Hazem A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2725 - +
  • [43] SYNTHESIS AND CHARACTERIZATION OF 1,2-DIPHENYL-3-MERCAPTOPROP-2-EN-1-ONE
    BEYER, L
    SITTEL, H
    PULST, M
    HOYER, E
    ZEITSCHRIFT FUR CHEMIE, 1974, 14 (12): : 469 - 470
  • [44] THE REACTION OF SODIUM 1,3-DIPHENYL-2-AZAPROPENIDE WITH 1,2-EPOXYCYCLOHEXANE
    BRADAMANTE, S
    FERRACCIOLI, R
    PAGANI, GA
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (03): : 515 - 518
  • [45] BIS(1,2-DIPHENYL-1,2-ETHYLENEDITHIOLATO)TRIMETHOXYPHOSPHINEIRON(IV)
    MIYAMAE, H
    SATO, S
    SAITO, Y
    SAKAI, K
    FUKUYAMA, M
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (DEC): : 3942 - 3944
  • [46] Synthesis of an enantiopure fluorous 1,2-diphenyl-1,2-diaminoethane
    Bayardon, J
    Sinou, D
    SYNTHESIS-STUTTGART, 2005, (03): : 425 - 428
  • [47] 1,2-Diphenyl-3,4-dihydronaphthalene
    Crawford, HM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 : 727 - 728
  • [48] 1,2-diphenyl-3-benzylguanidine hydrochloride
    Sudha, L
    Subramanian, K
    Selvan, JS
    Steiner, T
    Koellner, G
    Ramdas, K
    Srinivasan, N
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 86 - 88
  • [49] 3-METHOXY-1,2-DIPHENYL-2-PHOSPHOLENE 1-OXIDE
    GALDECKI, Z
    GLOWKA, ML
    GOLINSKI, B
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (FEB): : 461 - 463
  • [50] Synthesis and Characterization of Some Ni(II) and Cu(II) Complexes with 2-[(4-Aminophenyl)imino]-1, 2-diphenyl-1-ethanone
    Khalifa, K. M.
    Hamil, A. M.
    Gasem, A.
    Abdulsalam, A.
    E-JOURNAL OF CHEMISTRY, 2010, 7 (01) : 49 - 54