1,2-Diphenyl-2-(m-tolylamino)ethanone

被引:0
|
作者
Mendoza Merono, Rafael [1 ]
Napoles Esculary, Felix [2 ]
Menendez Taboada, Laura [1 ]
Garcia-Granda, Santiago [1 ]
机构
[1] Univ Oviedo, Fac Quim, Dept Quim Fis & Analit, E-33006 Oviedo, Spain
[2] Univ Oriente, Fac Ciencias Nat, Dept Quim, Santiago De Cuba, Cuba
关键词
D O I
10.1107/S1600536810013371
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C(21)H(19)NO, belongs to the family of alpha-aminoketones. The structure contains three benzene rings, two of which [the phenyl ring in the 1-position (B) and the methylaniline ring (A)] are nearly coplanar [dihedral angle = 5.4 (1)degrees], whereas the phenyl ring in the 2-position (C) is nearly normal to them [dihedral angles = 81.8 (1) and 87.0 (1)degrees for A/C and B/C, respectively]. The conformation of the N-H bond is syn to the C=O bond, favouring the formation of a centrosymmetric dimer of molecules in the crystal structure. The molecular packing is consolidated by this N-H center dot center dot center dot O hydrogen-bonding network.
引用
收藏
页码:O1107 / U379
页数:10
相关论文
共 50 条
  • [1] (Z)-1,2-Diphenyl-2-(phenylhydrazono)ethanone
    Bouchama, Abdelaziz
    Bendaas, Abderrahmen
    Bouacida, Sofiane
    Yahiaoui, Messaoud
    Benard-Rocherulle, Patricia
    Djedouani, Amel
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O1990 - O1992
  • [2] Structure and Electrochemical Studie of (Z)-1,2-Diphenyl-2-(phenylhydrazono)ethanone.
    Djedouani, Amel
    Yahiaoui, Massouede
    Bendaas, Abderrahmen
    Bouacida, Soufiane
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2009, 65 : S223 - S223
  • [3] 1,2-Diphenyl-2-{[1-(quinoxalin-3-yl)propylidene]-hydrazono}ethanone
    Liu, Qi-Kui
    Ma, Jian-Ping
    Huang, Ru-Qi
    Dong, Yu-Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2646 - O2647
  • [4] STRUCTURES OF (Z)-1,2-DIPHENYL-2-(4-TOLYLVINYL) AND (E)-1,2-DIPHENYL-2-(4-TOLYLVINYL) BROMIDE
    LUO, YG
    BARTON, RJ
    ROBERTSON, BE
    LEE, CC
    WANIGASEKERA, D
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 73 - 76
  • [5] 1,2-Diphenyl-2-[(1-phenylethyl)-amino]ethanol
    Hou, Qing-Gao
    Zhao, Chang-Qiu
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2220 - +
  • [6] Synthesis and oxidation of (E)-1,2-diphenyl-2-(arylimino) ethanol derivatives
    Aiube, Zakaria H.
    Najiam, Sabah T.
    Kadhum, Abdul Amir H.
    RESEARCH ON CHEMICAL INTERMEDIATES, 2013, 39 (06) : 2351 - 2355
  • [7] Synthesis and oxidation of (E)-1,2-diphenyl-2-(arylimino) ethanol derivatives
    Zakaria H. Aiube
    Sabah T. Najiam
    Abdul Amir H. Kadhum
    Research on Chemical Intermediates, 2013, 39 : 2351 - 2355
  • [8] 1,2-Diphenyl-2-(phenyldiazenyl)-2-tosylethanone, an example of a fungicide containing a sulfonyl group
    Wolf, WM
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 (12) : 1444 - 1446
  • [9] Multi-component synthesis of 1,2-diphenyl-2-[2-(5-aryl-6H-1,3,4-thiadiazin-2-yl)hydrazono]ethanone
    Aychiluhim, Tewodros Birhanu
    Vedula, Rajeswar Rao
    HETEROCYCLIC COMMUNICATIONS, 2014, 20 (04) : 239 - 242
  • [10] 1,2-Diphenyl-2-[4-(4-pyridyl)benzylidenehydrazono]ethan-1-one
    Patra, Goutam Kumar
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O1810 - U2534