Calcium-catalyzed intermolecular hydrophosphination

被引：172
|
作者：
Crimmin, Mark R.
Barrett, Anthony G. M.
Hill, Michael S.
Hitchcock, Peter B.
Procopiou, Panayiotis A.
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England
[3] GlaxoSmithKline Med Res Ctr, Stevenage SG1 2NY, Herts, England
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 12期
关键词：
D O I：
10.1021/om070200k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The beta-diketiminato complex [{HC(C(Me)(2)N-2,6-(Pr2C6H3)-Pr-i)(2)}Ca{N(SiMe3)(2)}(THF)] effects intermolecular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.
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页码：2953 / 2956
页数：4
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