Electrochemistry of -N(CF3)2 compounds.

被引：0

作者：

Ignat'ev, NV ^{[1
]}

Hilarius, V ^{[1
]}

Heider, U ^{[1
]}

Kühner, A ^{[1
]}

Schmidt, M ^{[1
]}

Kucherina, A ^{[1
]}

Sartori, P ^{[1
]}

机构：

[1] Merck KGaA, D-64271 Darmstadt, Germany

来源：

REACTIVE INTERMEDIATES IN ORGANIC AND BIOLOGICAL ELECTROCHEMISTRY | 2001年 / 2001卷 / 14期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

N,N-Bis(trifluoromethyl)perfluoroalkanesulfonamides can be synthesized via electrochemical fluorination in anhydrous hydrogen fluoride (Simons process). These compounds are convenient starting materials for the generation of N-(CF3)(2) anion. The anodic substitution reactions of organic compounds with N-(CF3)(2) anion were studied.

引用

页码：113 / 116

页数：4

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