Synthesis, characterization, crystal structure and electrochemical studies of ionic iron(III) dipicolinato complex

被引：3

作者：

Ghasemi, Fatemeh ^{[1
]}

Ghasemi, Khaled ^{[1
]}

Rezvani, Ali Reza ^{[1
]}

Rosli, Mohd Mustaqim ^{[2
]}

Razak, Ibrahim Abdul ^{[2
]}

机构：

[1] Univ Sistan & Baluchestan, Dept Chem, Fac Sci, POB 98135-674, Zahedan, Iran

[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Grp, George Town 11800, Malaysia

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1144卷

关键词：

2,6-Pyridinedicarboxylic acid; Iron(III) complex; Crystal structure; Noncovalent interactions; PYRIDINE-2,6-DICARBOXYLIC ACID; O-PHENYLENEDIAMINE; PROTON-TRANSFER; BIS(PYRIDINE-2,6-DICARBOXYLATO) IRON(III); BIS(DIPICOLINATO)FERRATE(III) DIHYDRATE; CATALYTIC-OXIDATION; CHEMISTRY; IRON; METFORMIN; COMPOUND;

D O I：

10.1016/j.molstruc.2017.05.044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The new complex (NH4)[Fe(dipic)(2)] (1) (dipicH(2) = 2,6-pyridinedicarboxylic acid), was synthesized and characterized by elemental analysis, FTIR and UV-Vis spectroscopy and single crystal X-ray method. The crystal system is tetragonal with space group I4(1)/a. The Fe-III ion and the N atom of the ammonium cation are located on a crystallographic fourfold rotoinversion axis ((4) over bar). The N-H center dot center dot center dot O and C-H center dot center dot center dot O intermolecular hydrogen bonding and pi center dot center dot center dot pi stacking interactions play an important role in the formation of a 3-dimensional anion-cation network and stabilization of the crystal structure. The redox behavior of the complex was also investigated by cyclic voltammetry. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：186 / 190

页数：5

共 50 条

[31] The synthesis, crystal structure, and spectroscopic characterization of a tetrakis(μ-N,N′-diarylformamidinato)chlorodirhenium(III,III) cationic complex
Barclay, T
Eglin, JL
Smith, LT
POLYHEDRON, 2001, 20 (9-10) : 767 - 771
[32] Synthesis, characterization, and electrochemical studies of a ruthenium organometallic complex
Fleming, Morgan
Sienerth, Karl
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[33] Sonochemical synthesis and crystal structure of indium(III) complex as a modifier for electrochemical simultaneous determination of dopamine and acetylcholine
Beitollahi, Hadi
Akbarzadeh-T, Niloufar
Parsa, Asghar
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2020, 67 (07) : 1219 - 1229
[34] Synthesis, crystal structure, magnetic characterization and spectroscopic properties of a new dinuclear iron(III) complex asymmetrically bridged by a phenoxo and methoxo groups
Zeyrek, C. T.
Elmali, A.
Elerman, Y.
CRYSTAL RESEARCH AND TECHNOLOGY, 2006, 41 (05) : 510 - 516
[35] Synthesis and crystal structure of maricite and sodium iron(III) hydroxyphosphate
Bridson, JN
Quinlan, SE
Tremaine, PR
CHEMISTRY OF MATERIALS, 1998, 10 (03) : 763 - 768
[36] Synthesis and Crystal Structure of Maricite and Sodium Iron(III) Hydroxyphosphate
Bridson, J. N.
Quinlan, S. E.
Tremaine, P. R.
Chemistry of Materials, 10 (03):
[37] Synthesis, crystal structure and magnetism of iron(III) and manganese(III) dipicolinates with pyridinemethanols
Uhrecky, Robert
Pavlik, Jan
Ruzickova, Zdenka
Dlhan, L'ubor
Koman, Marian
Boca, Roman
Moncol, Jan
JOURNAL OF MOLECULAR STRUCTURE, 2014, 1076 : 10 - 19
[38] Synthesis and characterization of an iron(III) amine triphenolate coordination complex
Casey, Kerry
Steigen, Lauren
Williams, Ursula
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
[39] Synthesis and Characterization of Iron(III) Complex Derived from Benzilmonoxime
Soleimani, Esmaiel
Mitu, Liviu
ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (04) : 1557 - 1560
[40] SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF A NOVEL COMPLEX OF MALEIC-ACID WITH GADOLINIUM(III)
XUE, WM
ZHU, Y
YANG, RD
JOURNAL OF COORDINATION CHEMISTRY, 1992, 26 (03) : 199 - 204

← 1 2 3 4 5 →