Trimeric hexa-dimethyltin-functionalized selenotungstate [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18-

被引：13

作者：

Chen, Wei-Chao ^{[1
]}

Qin, Chao ^{[1
]}

Wang, Xin-Long ^{[1
]}

Wu, Cai-Xia ^{[1
]}

Li, Yang-Guang ^{[1
]}

Zang, Hong-Ying ^{[1
]}

Shao, Kui-Zhan ^{[1
]}

Su, Zhong-Min ^{[1
]}

Wang, En-Bo ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Minist Educ, Inst Funct Mat Chem,Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 16期

关键词：

BOND-VALENCE PARAMETERS; BIOLOGICAL-ACTIVITY; HETEROPOLYTUNGSTATES; NANOCLUSTERS; CLUSTER; POLYOXOTUNGSTATES; TUNGSTOPHOSPHATE; POLYOXOANIONS; TEMPLATE;

D O I：

10.1039/c6ce00377j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trimeric organic-inorganic hybrid selenotungstate(IV) [{Sn(CH3)(2)(CH3COO)}(3){Sn(CH3)(2)}(3){Se2W18O62(OH)(H2O)}(3)](18-) is composed of three Wells-Dawson-type {alpha-Se2W18} fragments and six {(CH3)(2)Sn2+} groups involving the first reported carboxyl-modified dimethyltin moieties, exhibiting photocatalytic H-2 evolution activity.

引用

页码：2820 / 2824

页数：5

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