Trimeric hexa-dimethyltin-functionalized selenotungstate [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18-

被引：13
|
作者：
Chen, Wei-Chao [1 ]
Qin, Chao [1 ]
Wang, Xin-Long [1 ]
Wu, Cai-Xia [1 ]
Li, Yang-Guang [1 ]
Zang, Hong-Ying [1 ]
Shao, Kui-Zhan [1 ]
Su, Zhong-Min [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Minist Educ, Inst Funct Mat Chem,Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China
来源：
CRYSTENGCOMM | 2016年 / 18卷 / 16期
关键词：
BOND-VALENCE PARAMETERS; BIOLOGICAL-ACTIVITY; HETEROPOLYTUNGSTATES; NANOCLUSTERS; CLUSTER; POLYOXOTUNGSTATES; TUNGSTOPHOSPHATE; POLYOXOANIONS; TEMPLATE;
D O I：
10.1039/c6ce00377j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The trimeric organic-inorganic hybrid selenotungstate(IV) [{Sn(CH3)(2)(CH3COO)}(3){Sn(CH3)(2)}(3){Se2W18O62(OH)(H2O)}(3)](18-) is composed of three Wells-Dawson-type {alpha-Se2W18} fragments and six {(CH3)(2)Sn2+} groups involving the first reported carboxyl-modified dimethyltin moieties, exhibiting photocatalytic H-2 evolution activity.
引用
收藏
页码：2820 / 2824
页数：5
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