Thermochemical Properties of Ph4Sb(OC(O)C10H15) and Ph3Sb(OC(O)C10H15)2

被引：4

作者：

Lyakaev, D. V. ^{[1
]}

Markin, A. V. ^{[1
]}

Khabarova, E. V. ^{[1
]}

Smirnova, N. N. ^{[1
]}

Knyazev, A. V. ^{[1
]}

Sharutin, V. V. ^{[2
]}

Sharutina, O. K. ^{[2
]}

机构：

[1] Lobachevsky State Univ Nizhny Novgorod, Nizhnii Novgorod 603022, Russia

[2] South Ural State Univ, Chelyabinsk 454080, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 09期

关键词：

calorimetry; combustion enthalpy; formation enthalpy; tetraphenylantimony adamantanecarboxylate; triphenylantimony bis(adamantanecarboxylate); TRIPHENYLANTIMONY BIS(1-ADAMANTANECARBOXYLATE); THERMODYNAMIC PROPERTIES; COMPLEXES; CYCLOOLIGOSTIBINE; LIGANDS; RANGE;

D O I：

10.1134/S0036024418090170

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The energy of combustion of crystalline adamantanecarboxylate of tetraphenylantimony and triphenylantimony bis(1-adamantanecarboxylate) is determined at 298.15 K using a combustion calorimeter with a static bomb. The combustion enthalpies of these substances in the crystalline state at 298.15 K are calculated using the obtained experimental data. Such standard functions of formation as H-f degrees and (f)G degrees are calculated for the studied compounds in the crystalline state at 298.15 K. The obtained thermochemical properties are analyzed, and their dependences on the molar mass of the substituent with antimony are determined.

引用

页码：1659 / 1663

页数：5

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