Reactions of tris(2-pyridyl)phosphines and tris(2-pyridyl)phosphine oxides with some electrophiles

被引：0

作者：

Uchida, Y ^{[1
]}

Matsuoka, K ^{[1
]}

Kajita, R ^{[1
]}

Kawasaki, Y ^{[1
]}

Oae, S ^{[1
]}

机构：

[1] INST HETEROATOM CHEM,MIHARA,OSAKA 587,JAPAN

来源：

HETEROATOM CHEMISTRY | 1997年 / 8卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of tris(2-pyridyl)phosphine or tris(2-pyridyl)phosphine oxide with electrophiles such as chlorine, bromine, deuterium chloride, or benzenediazonium chloride gave unusual coupling products, i.e., 5-chloro-, 5-bromo-, 5-deuterio-, or 5-phenylazo-2,2'-bipyridyls, respectively, as a major coupling product in each case. This is considered to be the result of electrophilic substitution on a pyridyl ring in a pentacovalent phosphorane intermediate formed in each reaction. (C) 1997 John Wiley & Sons, Inc.

引用

页码：439 / 449

页数：11

共 50 条

[41] Crystal structure of potassium tris[3-(2-pyridyl)pyrazolyl]hydroborate
Maija Nissinen
Terhi Alaviuhkola
Kari Rissanen
Jouni Pursiainen
Journal of Chemical Crystallography, 2006, 36 : 863 - 868
[42] TRICHLORO[TRIS(2-PYRIDYL)METHANOL]-RHODIUM(III) METHANOL (1/1)
ERTAN, A
ADOLFSSON, H
MOBERG, C
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 1761 - 1765
[43] UNUSUAL FORMATION OF 5-HALO-2,2'-BIPYRIDYLS BY TREATMENT OF TRIS(2-PYRIDYL)PHOSPHINE DERIVATIVES WITH HALOGENS
UCHIDA, Y
KAJITA, R
KAWASAKI, Y
OAE, S
TETRAHEDRON LETTERS, 1995, 36 (23) : 4077 - 4080
[44] Di(2-pyridyl)phenylamine and (2-pyridyl)-N-piperidine
Wibaut, JP
Tilman, G
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1933, 52 : 987 - 990
[45] COMPLEXES OF TRIS((2-PYRIDYL)ALKYL)AMINES WITH LITHIUM AND SODIUM-SALTS
BROWNSTEIN, SK
PLOUFFE, PY
BENSIMON, C
TSE, J
INORGANIC CHEMISTRY, 1994, 33 (02) : 354 - 358
[46] Crystal structure of potassium tris[3-(2-pyridyl)pyrazolyl]hydroborate
Nissinen, Maija
Alaviuhkola, Terhi
Rissanen, Kari
Pursiainen, Jouni
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2006, 36 (12) : 863 - 868
[47] Steric Effects on the Structures, Reactivity, and Coordination Chemistry of Tris(2-pyridyl)aluminates
Garcia-Rodriguez, Raul
Wright, Dominic S.
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (42) : 14949 - 14957
[48] The elusive tripodal tris(2-pyridyl)borate ligand: a strongly coordinating tetraarylborate
Cui, Chengzhong
Lalancette, Roger A.
Jaekle, Frieder
CHEMICAL COMMUNICATIONS, 2012, 48 (55) : 6930 - 6932
[49] Dual emissive Ln(III)-Ag(I) heterometallic chains based on tris(2-pyridyl)phosphine oxide
Bryleva, Yuliya A.
Rakhmanova, Mariana I.
Artem'ev, Alexander V.
Baranov, Andrey Yu.
Glinskaya, Ludmila A.
NEW JOURNAL OF CHEMISTRY, 2024, 48 (14) : 6430 - 6437
[50] Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide: Synthesis and cytotoxic activity evaluation
Artem'ev, Alexander V.
Eremina, Julia A.
Lider, Elizaveta V.
Antonova, Olga V.
Vorontsova, Elena V.
Bagryanskaya, Irina Yu.
POLYHEDRON, 2017, 138 : 218 - 224

← 1 2 3 4 5 →