Corrosion behavior of two candidate PEMFC's bipolar plate materials

被引:5
|
作者
Allahkaram, Saeed Reza [1 ]
Mohammadi, Namdar [2 ]
机构
[1] Univ Tehran, Coll Engn, Sch Met & Mat Engn, Tehran, Iran
[2] Islamic Azad Univ, Sci & Res Branch, Dept Mat Engn, Tehran, Iran
关键词
Corrosion; Failure investigation; Degradation; Coatings and linings; Monitoring; Development; ELECTROCHEMICAL NOISE; LEAD DIOXIDE; FUEL-CELLS; PITTING CORROSION; STEEL;
D O I
10.1108/ACMM-05-2015-1540
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Purpose - This paper aims to evaluate corrosion behavior of bare and PbO2-coated stainless steel 316L, as prospective candidates for bipolar plates, in simulated proton exchange membrane fuel cell's (PEMFC's) environment under operating potentials. Design/methodology/approach - A set of potentiodynamic, as well as potentiostatic, electrochemical experiments was carried out under both anodic and cathodic potentials. Gathered data were analyzed via fast Fourier transform algorithm for further investigation. X-ray diffraction analysis was also used for determining coating characteristics upon completion of electrochemical experiments. Findings - Results revealed that bare SS316L is a better candidate for bipolar plate material under anodic potential, as it is cathodically protected. However, PbO2-coated SS316L is favorable under cathodic potential, as bare specimen will suffer localized corrosion in the form of pitting. Originality/value - This research strives to promote the use of electrochemical noise measurement for practical corrosion monitoring of coated bipolar plates in fuel cells.
引用
收藏
页码:293 / 298
页数:6
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