Study of the midinfrared and CH-stretching regions of CH2=C-13=CH2

被引：2

作者：

Hegelund, F ^{[1
]}

Burger, H ^{[1
]}

Polanz, O ^{[1
]}

机构：

[1] UNIV GESAMTHSCH WUPPERTAL,FACHBEREICH 9,D-42097 WUPPERTAL,GERMANY

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1996年 / 175卷 / 01期

关键词：

D O I：

10.1006/jmsp.1996.0018

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Infrared spectra of [2-C-13]allene (H2C=C-13=CH2) between 1300 and 3300 cm(-1) covering the v(7), v(9) + v(11), 2 v(10), v(6), v(5), and v(8) bands have been studied at a resolution of ca. 0.004 cm(-1). Spectroscopic constants are derived from single subband analysis of these bands and various perturbations are discussed. A detailed analysis of the v(7)/v(9)(1) + v(11)(1) band system is performed from a model taking into account Fermi resonance between v(7) and v(9)(1) + v(11)(1), higher order anharmonic resonance between v(7) and 4v(11)(2), higher order anharmonic resonance between v(9)(1) + v(11)(1) and 4v(11)(2), and rotational I-type resonances within v(9) + v(11). The 2v(10) band has been analyzed using a model taking into account rotational I-type resonances within 2v(10) and (x,y)-Coriolis interactions with v(4) + v(10) and v(7) + v(11). Both analyses yield a number of spectroscopic constants for the levels included in the models as well as various interaction constants. (C) 1996 Academic Press, Inc.

引用

页码：142 / 157

页数：16

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