Synthesis and Reactivity of a Neutral, Three-Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation

被引：9
|
作者：
Kelly, Colin M. [1 ]
Kwon, Doo-Hyun [2 ]
Ferguson, Michael J. [3 ]
Bischof, Steven M. [4 ]
Sydora, Orson L. [4 ]
Ess, Daniel H. [2 ]
Stradiotto, Mark [1 ]
Turculet, Laura [1 ]
机构：
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada
[2] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[3] Univ Alberta, Dept Chem, Xray Crystallog Lab, Edmonton, AB T6G 2G2, Canada
[4] Chevron Phillips Chem Co LP, Res & Technol, Kingwood, TX 77339 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 48期
基金：
加拿大自然科学与工程研究理事会;
关键词：
amido ligation; coordination modes; density functional calculations; low-coordinate complexes; platinum; C-H; MIGRATORY INSERTION; BOND FORMATION; METAL-OXYGEN; ACTIVATION; PT(II); DIHYDROGEN; ROTATION; BASICITY; LIGANDS;
D O I：
10.1002/anie.201506871
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A crystallographically characterized three-coordinate, formally 14 electron PtII complex 1 featuring terminal amido ligation is reported. Computational analysis revealed relatively weak pi donation from the amide lone pair to platinum and supports a 14-electron assignment for 1. Stoichiometric reactivity studies confirmed the viability of net O - H and C - H addition across, as well as isonitrile insertion into, the terminal platinum-amido linkage of 1.
引用
收藏
页码：14498 / 14502
页数：5
相关论文
共 50 条
  • [31] Convenient synthesis and crystal structure of a monomeric zinc hydride complex with a three-coordinate metal center
    Spielmann, Jan
    Piesik, Dirk
    Wittkamp, Bernd
    Jansen, Georg
    Harder, Sjoerd
    CHEMICAL COMMUNICATIONS, 2009, (23) : 3455 - 3456
  • [32] Soft bending modes of terminal chlorides in gaseous two- and three-coordinate Cu(II)-Cl species
    Ystenes, BK
    Jensen, VR
    INORGANIC CHEMISTRY, 1999, 38 (18) : 3985 - 3993
  • [33] Three-coordinate Bis(N-heterocyclic carbene)iron(0) complexes with alkene and alkyne ligation: Synthesis and characterization
    Wang, Lijun
    Cheng, Jun
    Ma, Yingjie
    Chen, Qi
    Leng, Xuebing
    Deng, Liang
    POLYHEDRON, 2021, 197
  • [34] Neutral, three-coordinate, chelating diamide aluminum complexes: Catalysts/initiators for synthesis of telechelic oligomers and high polymers
    Chakraborty, D
    Chen, EYX
    ORGANOMETALLICS, 2002, 21 (07) : 1438 - 1442
  • [35] A Low-Spin Three-Coordinate Cobalt(I) Complex and Its Reactivity toward H2 and Silane
    Choi, Jonghoon
    Lee, Yunho
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (21) : 6938 - 6942
  • [36] Four-coordinate disilyl cobalt(II) complexes with NHC ligation: Synthesis, characterization, and reactivity
    Zhou, Lan
    Wang, Dongyang
    Yang, Chengbo
    Deng, Liang
    CHINESE CHEMICAL LETTERS, 2024, 35 (03)
  • [37] Synthesis, structure, and reactivity of diazoketiminato complexes of platinum(II) and palladium(II): Cytotoxic properties of a platinum complex
    Pratihar, Jahar Lal
    Shee, Biswaranjan
    Pattanayak, Poulami
    Patra, Debprasad
    Bhattacharyya, Arindam
    Puranik, Vedavati G.
    Hung, C. H.
    Chattopadhyay, Surajit
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (27) : 4272 - 4281
  • [38] Preparation and reactivity studies of the novel three-coordinate alkyl complexes of Ni(I) and their cationic Ni(II) derivatives.
    Hillhouse, GL
    Mindiola, DJ
    Kitiachvili, KD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U692 - U692
  • [39] Three-Coordinate Iron(0) Complexes with N-Heterocyclic Carbene and Vinyltrimethylsilane Ligation: Synthesis, Characterization, and Ligand Substitution Reactions
    Cheng, Jun
    Chen, Qj
    Leng, Xuebing
    Ye, Shengfa
    Deng, Liang
    INORGANIC CHEMISTRY, 2019, 58 (19) : 13129 - 13141
  • [40] Three-coordinate cobalt(IV) and cobalt(V) imido complexes with N-heterocyclic carbene ligation: Synthesis, structure, and their distinct reactivity in C-H bond amination
    Deng, Liang, 1600, American Chemical Society (136):
12345