Synthesis, spectroscopy and electrochemistry of a new phthalonitrile derivative with substituted PDT-TTF unit

被引：0
|
作者：
Hua, YY
Shen, YJ [1 ]
Xu, X
Li, XH
Li, YF
机构：
[1] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2003年 / 7卷 / 03期
关键词：
substituted phthallonitrile; PDT-TTF; ring expansion reaction; cyclic voltammetry; single crystal; X-ray determination;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A phthalonitrile derivative with a substituted propylenedithio-tetrathiafulvalene (PDT-TTF) unit was synthesized and characterized. H-1 NMR spectra disclosed an unexpected ring expansion reaction, by which the title compound was formed. Its crystal structure was determined by single crystal X-ray diffraction. The cyclic voltammogram and differential pulse voltammogram of the title compound showed two couples of redox peaks arising from TTF, one additional irreversible oxidation peak and one irreversible reduction peak. Copyright (C) 2003 Society of Porphyrins & Phthalocyanines.
引用
收藏
页码：191 / 198
页数：8
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