Synthesis, spectroscopy, and electrochemistry of metallophthalocyanines substituted by propylenedithiotetrathiafulvalene derivatives

被引：10
|
作者：
Hu, YY
Lai, GQ
Shen, YJ [1 ]
Li, YF
机构：
[1] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
[2] Hangzhou Normal Coll, Inst New Mat, Zhejiang 310036, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
MONATSHEFTE FUR CHEMIE | 2004年 / 135卷 / 09期
关键词：
propylenedithiotetrathiafulvalene; metallophthalocyanine; optical spectroscopy; cyclic voltammetry;
D O I：
10.1007/s00706-004-0200-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Zinc(II) and magnesium(II) phthalocyanines bearing four substituted propylenedithiotetrathiafulvalene (PDT-TTF) units were synthesized and characterized by NMR, MS, EA, and UV/VIS spectra. The absorption peaks of two target molecules were hypsochromically shifted compared with the phthalocyanine parent compound. Studies using cyclic voltammetry indicated that introduction of Zn and Mg as central metals enhanced the electronwithdrawing between the phthalocyanine core and the PDT-TTF unit, thus losing one electron to form (PDT-TTF)(+) becomes more difficult.
引用
收藏
页码：1167 / 1172
页数：6
相关论文
共 50 条
  • [1] Synthesis, Spectroscopy, and Electrochemistry of Metallophthalocyanines Substituted by Propylenedithiotetrathiafulvalene Derivatives
    Yingyu Hu
    Guoqiao Lai
    Yongjia Shen
    Yongfang Li
    Monatshefte für Chemie / Chemical Monthly, 2004, 135 : 1167 - 1172
  • [2] Functional fluoro substituted tetrakis-metallophthalocyanines:: Synthesis, spectroscopy, electrochemistry and spectroelectrochemistry
    Gunsel, Armagan
    Kandaz, Mehmet
    Koca, Atif
    Salih, Bekir
    JOURNAL OF FLUORINE CHEMISTRY, 2008, 129 (08) : 662 - 668
  • [3] Electrochemistry and spectroelectrochemistry of tetra-α-substituted metallophthalocyanines
    Ou, Zhongping
    Jiang, Zhou
    Chen, Naisheng
    Huang, Jinling
    Shen, Jing
    Kadish, Karl M.
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2008, 12 (10) : 1123 - 1133
  • [4] Synthesis and electrochemistry of new octa-substituted metal-free and metallophthalocyanines
    Acar, Irfan
    Saka, Ece Tugba
    Topcu, Saim
    Biyiklioglu, Zekeriya
    Kantekin, Halit
    Kamiloglu, Ayse Aktas
    JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (10) : 1847 - 1858
  • [5] Synthesis, characterisation and electrochemistry of derivatisable novel -tetra 7-oxycoumarin-3-carboxylate-substituted metallophthalocyanines
    Dur, Eyup
    Ozkaya, Ali Riza
    Bulut, Mustafa
    SUPRAMOLECULAR CHEMISTRY, 2011, 23 (05) : 379 - 388
  • [6] Synthesis of nonperipherally tetra-[5-(diethylamino)-2-formylphenoxy] substituted metallophthalocyanines and their electrochemistry
    Keles, Turgut
    Unluer, Dilek
    Biyiklioglu, Zekeriya
    Unver, Yasemin
    TURKISH JOURNAL OF CHEMISTRY, 2021, 45 (01) : 17 - +
  • [7] Synthesis and (Spectro) electrochemistry of Ferrocenyl-Substituted Pyridine Derivatives
    Podolan, Gabriel
    Hettmanczyk, Lara
    Hommes, Paul
    Sarkar, Biprajit
    Reissig, Hans-Ulrich
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2015, 2015 (33) : 7317 - 7323
  • [8] Synthesis, Electrochemistry, Spectroelectrochemistry, and Electrochromism of Metallophthalocyanines Substituted with Four (2,4,5-trimethylphenyl)ethynyl Groups
    Ozcan, Sevgi
    Kobak, Rabia Zeynep
    Budak, Ozlem
    Koca, Atif
    Bayir, Zehra Altuntas
    ELECTROANALYSIS, 2022, 34 (10) : 1610 - 1620
  • [9] Synthesis, electrochemistry, spectroelectrochemistry and electropolymerization of metal-free and metallophthalocyanines
    Cakir, Volkan
    Kantekin, Halit
    Biyiklioglu, Zekeriya
    Koca, Atif
    POLYHEDRON, 2014, 81 : 525 - 533
  • [10] meso-substituted octabromoporphyrins: Synthesis, spectroscopy, electrochemistry and electronic structure
    Hariprasad, G
    Dahal, S
    Maiya, BG
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (16): : 3429 - 3436
12345