Supported NHC-Benzimi@Cu Complex as a Magnetically Separable and Reusable Catalyst for the Multicomponent and Click Synthesis of 1,4-Disubstituted 1,2,3-Triazoles via Huisgen 1,3-Dipolar Cycloaddition

被引:22
|
作者
Pawar, Arvind [1 ,3 ]
Gajare, Shivanand [2 ]
Jagdale, Ashutosh [1 ]
Patil, Sandip [1 ]
Chandane, Wilson [2 ]
Rashinkar, Gajanan [2 ]
Patil, Suresh [1 ]
机构
[1] Padmabhushan Dr Vasantraodada Patil Coll, Dept Chem, Tasgaon 416312, MS, India
[2] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India
[3] Shikshanmaharshi Dr Bapuji Salunkhe Coll, Dept Chem, Miraj 416412, MS, India
关键词
Magnetically retrievable nanocatalyst; Click reaction; Copper iodide; 1,2,3-triazoles; Reusability; N-HETEROCYCLIC CARBENES; HIGHLY EFFICIENT; METAL-COMPLEXES; SULFONYL AZIDE; SILICA; CHEMISTRY; ALKYNE; ACID; NANOPARTICLES; LIGANDS;
D O I
10.1007/s10562-021-03772-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we report a novel magnetically separable silica coated copper nano-magnetite NHC-benzimi@Cu complex as heterogeneous catalyst for the multicomponent click reaction via Huisgen 1,3-dipolar cycloaddition reaction of alkyl or aryl halide, sodium azide and terminal alkyne, which affords variousl,4-disubstituted 1,2,3-triazoles. The multistep prepared nano catalyst has been characterized by various spectroscopic methods such as FT-IR, TGA, EDX, XRD, TEM and VSM. The heterogeneous nano catalyst structures coated on the copper surface are responsible for the excellent catalyst performances in the reaction. The reusability of the catalyst makes the present protocol more fascinating from an environmental and economic point of view. [GRAPHICS] .
引用
收藏
页码:1854 / 1868
页数:15
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