Isomorphic Structural Transition in the β-Pyrochlore Oxide Superconductor KOs2O6

被引:11
|
作者
Yamaura, Jun-ichi [1 ]
Takigawa, Masashi [1 ]
Yamamuro, Osamu [1 ]
Hiroi, Zenji [1 ]
机构
[1] Univ Tokyo, Inst Solid State Phys, Chiba 2778581, Japan
关键词
pyrochlore oxide; rattling; structural transition; heat capacity; X-ray diffraction; NMR; CRYSTAL-STRUCTURE;
D O I
10.1143/JPSJ.79.043601
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A phase transition observed at T-p = 7.65 K in the beta-pyrochlore oxide superconductor KOs2O6 is studied by means of heat capacity, K-39-NMR, and X-ray diffraction measurements using high-quality single crystals. We find evidence of an isomorphic structural transition at T-p without the off-center freezing of the K ion even below T-p. It is possibly related to the rattling motion of the K ion in an oversized atomic cage.
引用
收藏
页数:4
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