Ni-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Unactivated Phenol and Phenylmethanol Derivatives

被引：18
|
作者：
Chen, Quan [1 ]
Wu, Aizhen [1 ]
Qin, Shengxiang [1 ]
Zeng, Meiqi [1 ]
Le, Zhiping [1 ]
Yan, Zhaohua [1 ]
Zhang, Hua [1 ]
机构：
[1] Nanchang Univ, Coll Chem, 999 Xuefu Ave, Nanchang 330031, Jiangxi, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 17期
基金：
中国国家自然科学基金;
关键词：
decarboxylative cross-coupling; C-O bond functionalization; nickel-catalyzed; phenol derivatives; polyfluorobiaryls; C-O BOND; AROMATIC CARBOXYLATE SALTS; H BONDS; NICKEL CATALYSIS; DIRECT ARYLATION; BIARYL SYNTHESIS; ARYL HALIDES; ACTIVATION; CLEAVAGE; ACIDS;
D O I：
10.1002/adsc.201800729
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A Ni-catalyzed decarboxylative cross-coupling of potassium polyfluorobenzoates with unactivated phenol and phenylmethanol derivatives is described. This novel transformation provides a practical and efficient protocol towards the synthesis of important polyfluorobiaryls and polyfluorinated diarylmethanes, and greatly enlarges the range of electrophiles utilized in decarboxylative coupling. Remarkably, preliminary mechanistic studies indicated the essential role of Zn(OAc)(2) might lie in the enhancement of decarboxylation step.
引用
收藏
页码：3239 / 3244
页数：6
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