Ruthenium-birhodanine complex supported over fibrousphosphosilicate for photocatalytic CO2 reduction to formate

被引：12

作者：

Zhiani, Rahele ^{[1
]}

Khoobi, Mehdi ^{[2
,3
]}

Sadeghzadeh, Seyed Mohsen ^{[1
]}

机构：

[1] Islamic Azad Univ, Fac Sci, Dept Chem, Neyshabur Branch, Neyshabur, Iran

[2] Univ Tehran Med Sci, Inst Pharmaceut Sci, Tehran 1417614411, Iran

[3] Univ Tehran Med Sci, Fac Pharm, Dept Pharmaceut Biomat, Tehran, Iran

来源：

CATALYSIS TODAY | 2020年 / 340卷

关键词：

Phosphosilicate; KCC-1; Nano catalyst; One-pot synthesis; Green chemistry; Nanoparticle; AZIDE-ALKYNE CYCLOADDITION; METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE REDUCTION; CLICK CHEMISTRY; EFFICIENT; CATALYSTS; 1,2,3-TRIAZOLES; CONSTRUCTION; EVOLUTION; POLYMERS;

D O I：

10.1016/j.cattod.2018.09.034

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this work we report the design and synthesis of high-surface-area nanocatalysts by reaction between tripolyphosphate (TPP) and tetraethyl orthosilicate (TEOS) and then the complex ruthenium acetate anchored over the click modified ligand of fibrous phosphosilicate (FPS), forms a new highly efficient nano catalyst that shows excellent catalytic performance within CO2 reduction to formate under visible-light irradiation. The FPS/Ligand/Ru nanocatalyst was thoroughly characterized by Fourier transform infrared spectra (FTIR), Powder X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), Energy dispersive X-ray spectroscopy (EDX), and N-2 adsorption/desorption study.

引用

页码：197 / 203

页数：7

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