Photocatalytic reduction of CO2 in methanol to methyl formate over CuO-TiO2 composite catalysts

被引：184
|
作者：
Qin, Shiyue [1 ]
Xin, Feng [1 ]
Liu, Yuande [1 ]
Yin, Xiaohong [2 ]
Ma, Wei [2 ]
机构：
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[2] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin 300384, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2011年 / 356卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Photocatalysis; Photocatalytic reduction of CO2; Composite semiconductor; Methanol; Methyl formate; CARBON-DIOXIDE; PHOTOREDUCTION; TIO2; H-2; CONVERSION; GAS;
D O I：
10.1016/j.jcis.2010.12.034
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Photocatalytic reduction of CO2 on CuO-TiO2 composite catalysts in the presence of methanol to prepare methyl formate had been investigated. Methanol was used as sacrificial reagent to react with the photogenerated holes in the valence band, and CO2 was reduced by the electrons in the conduction band. CuO-TiO2 was optimized for CuO loading, preparation method and calcination temperature. The catalyst of 1.0CuO-TiO2, calcined at 450 degrees C and CTAB as a dispersant showed the highest overall activity. The heterojunction between CuO and TiO2 demonstrated with HRTEM played an important role in enhancing the photocatalytic activity. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码：257 / 261
页数：5
相关论文
共 50 条
  • [1] Photocatalytic reduction of CO2 over TiO2 based catalysts
    Kamila Kočí
    Lucie Obalová
    Zdeněk Lacný
    Chemical Papers, 2008, 62 : 1 - 9
  • [2] Photocatalytic reduction of CO2 over TiO2 based catalysts
    Koci, Kamila
    Obalova, Lucie
    Lacny, Zdenek
    CHEMICAL PAPERS, 2008, 62 (01): : 1 - 9
  • [3] Photocatalytic hydrogenation and reduction of CO2 over CuO/ TiO2 photocatalysts
    Edelmannova, Miroslava
    Lin, Kuan-Yu
    Wu, Jeffrey C. S.
    Troppova, Ivana
    Capek, Libor
    Koci, Kamila
    APPLIED SURFACE SCIENCE, 2018, 454 : 313 - 318
  • [4] Photocatalytic reduction of CO2 with H2O on CuO/TiO2 catalysts
    Li, Honghua
    Li, Cuixia
    Han, Lijun
    Li, Chunshan
    Zhang, Suojiang
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2016, 38 (03) : 420 - 426
  • [5] Photocatalytic Reduction of CO2 on TiO2 Catalysts
    Wang Huixiang
    Jiang Dong
    Wu Dong
    Li Debao
    Sun Yuhan
    PROGRESS IN CHEMISTRY, 2012, 24 (11) : 2116 - 2123
  • [6] Methanol Synthesis from CO2 Hydrogenation over Supported CuO/TiO2 Catalysts
    Liu Chao-Heng
    Guo Xiao-Ming
    Zhong Cheng-Lin
    Li Liang
    Hua Yu-Xi
    Mao Dong-Sen
    Lu Guan-Zhong
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2016, 32 (08) : 1405 - 1412
  • [7] Visible Light Driven Reduction of CO2 to Methanol Over CuO/TiO2 Nanofibers
    Tan, Heng
    Xiao, Sa
    Yao, Shu-Rong
    Xiong, Chun-Rong
    Jingxi Huagong/Fine Chemicals, 2019, 36 (06): : 1210 - 1216
  • [8] Addition of CuO to form CuO/TiO2 and CuO/ZnO heterojunctions for photocatalytic CO2 conversion to methanol
    Sahoo, Sunil Kumar
    Athira, P.
    Ray, Koustuv
    Pandey, Dharmendra
    CHEMICAL PHYSICS LETTERS, 2024, 856
  • [9] ELECTROCHEMICAL-BEHAVIOR OF CUO-TIO2 CATALYSTS
    TRANCHANT, A
    MESSINA, R
    PERICHON, J
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 1986, 16 (02) : 281 - 286
  • [10] A Study of Low-Temperature CO Oxidation over Mesoporous CuO-TiO2 Nanotube Catalysts
    Zedan, Abdallah F.
    Allam, Nageh K.
    AlQaradawi, Siham Y.
    CATALYSTS, 2017, 7 (05):
12345