{4′-[4-(4,4′-Bipyridin-1-ylmethyl)phenyl]-2,2′:6′,2"-terpyridine}chloridoplatinum(II) bis(perchlorate) acetonitrile disolvate sesquihydrate

被引：2
|
作者：
Zhang, Guiju [1 ]
Li, Quan [1 ]
Fu, Wenfu [1 ]
Wang, Daqi [2 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[2] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
ACCEPTOR GROUPS; DONOR;
D O I：
10.1107/S1600536810017782
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [PtCl(C(32)H(24)N(5))](ClO(4))(2)center dot 2CH(3)CN center dot 1.5H(2)O, comprises two unique Pt(II) complex cations, four perchlorate anions, four acetonitrile solvent molecules and three water molecules. The Pt atom is four-coordinated by a tridentate chelating 2,2': 6',2 ''-terpyridine ligand and a chloride ion in a square-planar geometry with modest distortion imposed by the constraint of the terpyridyl ligand. The r.m.s. deviations from the plane comprising the four ligand donor atoms and the Pt atom are 0.0381 and 0.0472 angstrom in the two complex cations.
引用
收藏
页码：M681 / U815
页数：19
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