Catalytic oxidation of alpha-carbon of ethers utilizing binuclear copper(II) complex of 7-azaindole

被引：19

作者：

Minakata, S

Imai, E

Ohshima, Y

Inaki, K

Ryu, I

Komatsu, M

Ohshiro, Y

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

[2] KINKI UNIV, SCI & TECHNOL RES INST, OSAKA 577, JAPAN

来源：

CHEMISTRY LETTERS | 1996年 / 01期

关键词：

D O I：

10.1246/cl.1996.19

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of benzyl ethyl ether with a catalytic amount of binuclear copper(II) complex of 7-azaindole 1 under oxygen atmosphere at 80 degrees C produced ethyl benzoate in 10400% yield based on the catalyst, This reaction could be also applied to other ethers (e.g., alkyl benzyl ethers and dialkyl ethers) to give alpha-oxygenated products catalytically.

引用

页码：19 / 20

页数：2

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