The Phosphorus Selena Bromide α-P4Se3Br2

被引：2

作者：

Hoppe, Diana ^{[1
]}

Rau, Franz ^{[1
]}

Schlosser, Marc ^{[1
]}

Pfitzner, Arno ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 02期

关键词：

Phosphorus; Selenium; Bromine; Cage molecules; X-ray diffraction; MOLECULAR STRUCTURE; CRYSTAL-STRUCTURE; BETA-P4S3I2; TRISULFIDE; THIOIODIDE; ISOMER;

D O I：

10.1002/zaac.200900345

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Yellow crystals of the phosphorus selena bromide alpha-P4Se3Br2, [monoclinic, C2/c, Z = 8 a = 12.724(3) angstrom, b = 14.732(3) angstrom, c = 12.553(3) angstrom, beta = 116.60(3)degrees] were obtained front the reaction of P4Se3 and bromine at 80 degrees C in sealed glass ampoules. The crystal structure features discrete molecules of the formula alpha-P4Se3Br2 according to the well-known alpha-form of P(4)Ch(3)I(2) molecules (Ch = S, Se).

引用

页码：305 / 308

页数：4

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