Synthesis of [n]Rotaxanes by Template-Directed Clipping: The Role of the Dialkylammonium Recognition Sites

被引：43
|
作者：
Yin, Jun [1 ]
Dasgupta, Suvankar [1 ]
Wu, Jishan [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 08期
关键词：
THERMODYNAMIC CONTROL; INTERLOCKED MOLECULES; CATENANES; ROTAXANES; MACHINES; NANOVALVES; SHUTTLES; MUSCLES; DEVICES; DESIGN;
D O I：
10.1021/ol100256w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Linear and rectangular [n]rotaxanes were synthesized by template-directed clipping of heterocrown ether components onto the dumbbell-shaped molecules containing different dialkylammonium recognition sites. The effect of the structure of the dialkylammonium sites on the clipping efficiency was investigated, and selective clipping led to formation of a rectangular [4]rotaxane.
引用
收藏
页码：1712 / 1715
页数：4
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