Anodic stripping voltammetry of trace metals by batch injection analysis

被引：54
|
作者：
Brett, CMA [1 ]
Brett, AMO [1 ]
Tugulea, L [1 ]
机构：
[1] UNIV BUCHAREST,FAC PHYS,DEPT BIOPHYS,BUCHAREST,ROMANIA
来源：
ANALYTICA CHIMICA ACTA | 1996年 / 322卷 / 03期
关键词：
batch injection analysis; mercury film electrodes; anodic stripping voltammetry; trace metals; flow injection; cadmium; copper; lead; zinc;
D O I：
10.1016/0003-2670(95)00588-9
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The application of batch injection analysis to the determination of trace metals in samples of volume less than or equal to 100 mu l by square wave anodic stripping voltammetry has been investigated in detail, using a programmable electronic micropipette. The in situ formation of a mercury film on a glassy carbon electrode substrate, the influence of preconcentration time, injection rate and injected volume of analyte ions have been studied and optimised procedures are recommended. Results for zinc, cadmium, lead and copper are presented, with particular emphasis on lead and cadmium, and nanomolar detection limits corresponding to sub-picomole quantities found. Comparison is made with flow-injection analysis and with experiments at wall-jet electrodes in continuous flow.
引用
收藏
页码：151 / 157
页数：7
相关论文
共 50 条
  • [41] TRACE METAL CHARACTERIZATION IN AQUATIC ENVIRONMENTS BY ANODIC STRIPPING VOLTAMMETRY
    ALLEN, HE
    MATSON, WR
    MANCY, KH
    [J]. JOURNAL WATER POLLUTION CONTROL FEDERATION, 1970, 42 (04): : 573 - &
  • [42] ANODIC STRIPPING VOLTAMMETRY
    ELLIS, WD
    [J]. JOURNAL OF CHEMICAL EDUCATION, 1973, 50 (03) : A131 - &
  • [43] Batch injection analysis with adsorptive stripping voltammetry for the determination of traces of nickel and cobalt
    Brett, CMA
    Brett, AMO
    Tugulea, L
    [J]. ELECTROANALYSIS, 1996, 8 (07) : 639 - 642
  • [44] APPLICATION OF AN AUTORANGING AMPLIFIER IN THE SIMULTANEOUS DETERMINATION OF TRACE HEAVY-METALS BY ANODIC-STRIPPING VOLTAMMETRY
    BENYAAKOV, S
    LAZAR, B
    [J]. TALANTA, 1980, 27 (12) : 1061 - 1066
  • [45] Determination of trace metals by anodic stripping voltammetry using a bismuth-modified carbon nanotube electrode
    Hwang, Gil Ho
    Han, Won Kyu
    Park, Joon Shik
    Kang, Sung Goon
    [J]. TALANTA, 2008, 76 (02) : 301 - 308
  • [46] 4-ELECTRODE ANODIC STRIPPING VOLTAMMETRY FOR DETERMINATION OF TRACE METALS IN PRESENCE OF DISSOLVED-OXYGEN
    SCHIMPFF, WK
    MANCY, KH
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, : 37 - &
  • [47] DETERMINATION OF ARSENIC BY ANODIC STRIPPING VOLTAMMETRY AND DIFFERENTIAL PULSE ANODIC STRIPPING VOLTAMMETRY
    OLAUGHLI.JW
    FORSBERG, G
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, (AUG26): : 34 - 34
  • [48] The determination of heavy metals in human gallstone by anodic stripping voltammetry
    Bouropoulos, N
    Karavias, D
    Koutsoukos, PG
    [J]. ANALUSIS, 1996, 24 (03) : 89 - 92
  • [49] Antimony-film electrode for the determination of trace metals by sequential-injection analysis/anodic stripping voltarnmetry
    Guzsvany, Valeria
    Nakajima, Hizuru
    Soh, Nobuaki
    Nakano, Koji
    Imato, Toshihiko
    [J]. ANALYTICA CHIMICA ACTA, 2010, 658 (01) : 12 - 17
  • [50] Determination of heavy metals in honey by anodic stripping voltammetry at microelectrodes
    Sanna, G
    Pilo, MI
    Piu, PC
    Tapparo, A
    Seeber, R
    [J]. ANALYTICA CHIMICA ACTA, 2000, 415 (1-2) : 165 - 173
12345