Homogeneous mono- and bimetallic catalysts for the oxidation of cyclohexene

被引：2
|
作者：
Jiang, H [1 ]
Xu, Y [1 ]
Liao, SJ [1 ]
Yu, DR [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1998年 / 63卷 / 01期
基金：
中国国家自然科学基金;
关键词：
allylic oxidation; cyclohexene; homogeneous bimetallic catalyst;
D O I：
10.1007/BF02475448
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the absence of solvent, the first-row transition-metal acetylacetonate complexes and RuCl2(PPh3)(3) give fairly high turnovers for the allylic oxidation of cyclohexene under atmospheric pressure of oxygen. Synergetic effect is observed for the oxidation of cyclohexene by using M(acac)(n)-RuCl2(PPh3)(3) bimetallic catalysts.
引用
收藏
页码：179 / 183
页数：5
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