Electroacoustic study of adsorption of PEO on sunflower oil-in-water emulsion drops

被引：2

作者：

Kong, L ^{[1
]}

Beattie, JK ^{[1
]}

Hunter, RJ ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem F11, Sydney, NSW 2006, Australia

来源：

LANGMUIR | 2003年 / 19卷 / 03期

关键词：

D O I：

10.1021/la026034x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electroacoustic signals of sunflower oil-in-water emulsion droplets stabilized by sodium dodecyl sulfate (SDS) were affected by the adsorption of poly(ethylene oxide) (PEO). Large changes in the dynamic mobility of the coated oil droplets measured with an AcoustoSizer-II apparatus were observed. The results are interpreted with the aid of O'Brien's "gel layer" model, which gives an estimate of the elasticity and the approximate thicknesses of a dense inner and an extended outer adsorbed polymer layer. The thicknesses of both the inner and the outer layer increased smoothly with increasing concentration of polymer and the rate of increase increased with molar mass of the polymer with average molecular weights of 1500, 10 000, and 35 000.

引用

页码：540 / 547

页数：8

共 50 条

[1] Electroacoustic study of concentrated oil-in-water emulsions
Kong, L
Beattie, JK
Hunter, RJ
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 238 (01) : 70 - 79
[2] Release of odour active compounds from oxidised sunflower oil and its oil-in-water emulsion
van Ruth, SM
Roozen, JP
Jansen, FJHM
[J]. FRONTIERS OF FLAVOUR SCIENCE, 2000, : 292 - 299
[3] A Comparative Study Between an Oil-in-Water Emulsion and Nonlipid Eye Drops Used for Rewetting Contact Lenses
Guthrie, Sarah E.
Jones, Lyndon
Blackie, Caroline A.
Korb, Donald R.
[J]. EYE & CONTACT LENS-SCIENCE AND CLINICAL PRACTICE, 2015, 41 (06): : 373 - 377
[4] Electroacoustic study of the crystallization of n-eicosane oil-in-water emulsions
Djerdjev, AM
Beattie, JK
Hunter, RJ
[J]. LANGMUIR, 2003, 19 (17) : 6605 - 6610
[5] Electroacoustic determination of size and charge of sunflower oil-in-water emulsions made by high-pressure homogenising
Kong, LG
Beattie, JK
Hunter, RJ
[J]. CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2001, 40 (05) : 421 - 429
[6] On the origin of electrostatic and steric repulsion in oil-in-water emulsion films from PEO-PPO-PEO triblock copolymers
Gotchev, G.
Kolarov, T.
Khristov, Khr.
Exerowa, D.
[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2010, 354 (1-3) : 56 - 60
[7] Oil-in-water emulsion as a modifier of water reflectance
Otremba, Zbigniew
[J]. OPTICA APPLICATA, 2009, 39 (01) : 123 - 128
[8] CHARACTERIZATION AND SEPARATION OF OIL-IN-WATER EMULSION
Mandal, Ajay
Kumar, Pradeep
Choudhary, Rajiv
Maity, S. K.
[J]. CBEE 2009: PROCEEDINGS OF THE 2009 INTERNATIONAL CONFERENCE ON CHEMICAL, BIOLOGICAL AND ENVIRONMENTAL ENGINEERING, 2010, : 33 - +
[9] On the Boiling Mechanism of an Oil-in-Water Emulsion
Gasanov, B. M.
[J]. HIGH TEMPERATURE, 2022, 60 (01) : 68 - 72
[10] THE RHEOLOGY OF OIL-IN-WATER EMULSION - DISCUSSION
RICHARD, EW
TRAIN, D
HUTCHINSON, WP
AXON, A
[J]. JOURNAL OF PHARMACY AND PHARMACOLOGY, 1956, 8 (10) : 772 - 773

← 1 2 3 4 5 →