Polymer-supported azidoproazaphosphatrane: A recyclable catalyst for the room-temperature transformation of triglycerides to biodiesel

被引：32

作者：

Reddy, Chinta Reddy Venkat ^{[1
]}

Fetterly, Brandon M. ^{[1
]}

Verkade, John G. ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

来源：

ENERGY & FUELS | 2007年 / 21卷 / 04期

关键词：

D O I：

10.1021/ef070095r

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A promising route for the quantitative transesterification of soybean oil (SBO) with methanol to biodiesel (FAMES) at room temperature is described using the Merrifield resin-supported catalyst resin-N3P(MeNCH2CH2)(3)N. This catalyst was recycled 11 times, although its activity decreased with time. Factors possibly responsible for catalyst deactivation are presented. Interestingly, the polymer-supported catalyst was twice as active as the homogeneous analogue PhCH2N3P(MeNCH2CH2)(3)N in this reaction. The SBO/methanol ratio in our protocol was 1:33, and the biodiesel obtained from our protocol met the American Society for Testing and Materials (ASTM) D-874 standard for sulfated ash.

引用

页码：2466 / 2472

页数：7

共 50 条

[21] POLYMER-SUPPORTED CATALYSTS .2. POLYMER-SUPPORTED RUTHENIUM ACETATE AS AN OLEFIN HYDROGENATION CATALYST
NICOLAIDES, CP
COVILLE, NJ
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1984, 24 (03): : 375 - 387
[22] Waste Passion Fruit Peel as a Heterogeneous Catalyst for Room-Temperature Biodiesel Production
Tarigan, Juliati Br
Singh, Krishanjit
Sinuraya, Jenita S.
Supeno, Minto
Sembiring, Helmina
Tarigan, Kerista
Rambe, Siti Masriani
Karo-karo, Justaman A.
Sitepu, Eko K.
[J]. ACS OMEGA, 2022, 7 (09): : 7885 - 7892
[23] Polymer-supported zirconocene catalyst for ethylene polymerization
Meng, FH
Yu, GQ
Huang, BT
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1999, 37 (01) : 37 - 46
[24] A simple, recyclable, polymer-supported palladium catalyst for Suzuki coupling - An effective way to minimize palladium contamination
Shieh, WC
Shekhar, R
Blacklock, T
Tedesco, A
[J]. SYNTHETIC COMMUNICATIONS, 2002, 32 (07) : 1059 - 1067
[25] Recyclable polymer-supported Pd catalysts for aryl amination reactions
Guinó, M
Hii, KK
[J]. TETRAHEDRON LETTERS, 2005, 46 (43) : 7363 - 7366
[26] A polymer-supported Cinchona-based bifunctional sulfonamide catalyst: a highly enantioselective, recyclable heterogeneous organocatalyst
Youk, Sung Hun
Oh, Sang Ho
Rho, Ho Sik
Lee, Je Eun
Lee, Ji Woong
Song, Choong Eui
[J]. CHEMICAL COMMUNICATIONS, 2009, (16) : 2220 - 2222
[27] Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst
Clot-Almenara, Lidia
Rodriguez-Escrich, Carles
Pericas, Miquel A.
[J]. RSC ADVANCES, 2018, 8 (13): : 6910 - 6914
[28] Simply assembled and recyclable polymer-supported olefin metathesis catalysts
Jafarpour, L
Nolan, SP
[J]. ORGANIC LETTERS, 2000, 2 (25) : 4075 - 4078
[29] POLYMER IS MAGNETIC AT ROOM-TEMPERATURE
BORMAN, S
[J]. CHEMICAL & ENGINEERING NEWS, 1991, 69 (23) : 5 - 6
[30] A POLYMER-SUPPORTED DICHLORO(CYCLOPENTADIENYL)RHODIUM(III) CATALYST
TUNG, HS
BRUBAKER, CH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 216 (01) : 129 - 137

← 1 2 3 4 5 →