A New Quadruple Hydrogen-Bonding Module Based on Five-Membered Heterocyclic Urea Structure

被引：29
|
作者：
Hisamatsu, Yosuke [1 ]
Shirai, Naohiro [1 ]
Ikeda, Shin-ichi [1 ]
Odashima, Kazunori [1 ]
机构：
[1] Nagoya City Univ, Grad Sch Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 08期
关键词：
COMPLEXATION; FIDELITY; SELECTIVITY; STABILITY; ARRAYS;
D O I：
10.1021/ol100385b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N,N'-Di-4-triazolylurea (DTU) has developed as a new ADDA module and DTU forms a stable ADDA center dot DAAD heterocomplex with 2,7-diamido1,8-naphthyridine (DAN) (K-s = 2.6 x 10(5) M-1 in CHCl3). The K, value of the complex between DTU and DAN is 100-fold greater than that of the complex between N,N'-di-2-pyridylurea and DAN due to replacement of a pyridine ring with a 1,2,3-triazole ring.
引用
收藏
页码：1776 / 1779
页数：4
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