Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

被引：139

作者：

Marichev, Kostiantyn O. ^{[1
]}

Takacs, James M. ^{[1
]}

机构：

[1] Univ Nebraska Lincoln, Dept Chem, Lincoln, NE 68588 USA

来源：

ACS CATALYSIS | 2016年 / 6卷 / 04期

关键词：

borrowing hydrogen; aminations; ruthenium(II) complex; heterocycle synthesis; hydrogen autotransfer; ASTERISK-IR COMPLEX; BETA-AMINO ALCOHOLS; N-ALKYLATION; SELECTIVE ALKYLATION; (HETERO)AROMATIC AMINES; EFFICIENT CATALYSTS; IRIDIUM CATALYSTS; AROMATIC-AMINES; MILD CONDITIONS; DIAMINES;

D O I：

10.1021/acscatal.6b00175

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono-and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.

引用

页码：2205 / 2210

页数：6

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