Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

被引：139
|
作者：
Marichev, Kostiantyn O. [1 ]
Takacs, James M. [1 ]
机构：
[1] Univ Nebraska Lincoln, Dept Chem, Lincoln, NE 68588 USA
来源：
ACS CATALYSIS | 2016年 / 6卷 / 04期
关键词：
borrowing hydrogen; aminations; ruthenium(II) complex; heterocycle synthesis; hydrogen autotransfer; ASTERISK-IR COMPLEX; BETA-AMINO ALCOHOLS; N-ALKYLATION; SELECTIVE ALKYLATION; (HETERO)AROMATIC AMINES; EFFICIENT CATALYSTS; IRIDIUM CATALYSTS; AROMATIC-AMINES; MILD CONDITIONS; DIAMINES;
D O I：
10.1021/acscatal.6b00175
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono-and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols, and diamines lead to heterocyclic ring systems.
引用
收藏
页码：2205 / 2210
页数：6
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