Controllable Synthesis of Ruthenium Phosphides (RuP and RuP2) for pH-Universal Hydrogen Evolution Reaction

被引：85
|
作者：
Chang, Qingbo [1 ]
Ma, Jingwen [1 ]
Zhu, Yuanzhi [1 ]
Li, Zhen [1 ]
Xu, Danyun [1 ]
Duan, Xuezhi [2 ]
Peng, Wenchao [1 ]
Li, Yang [1 ]
Zhang, Guoliang [1 ]
Zhang, Fengbao [1 ]
Fan, Xiaobin [1 ]
机构：
[1] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Sch Chem Engn & Technol, State Key Lab Chem Engn, 135 Yaguan Rd, Tianjin 300354, Peoples R China
[2] East China Univ Sci & Technol, State Key Lab Chem Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2018年 / 6卷 / 05期
关键词：
ruthenium phosphides; one-step controlled synthesis; all pH range; Pt-like activity; Hydrogen evolution reaction; REACTION ELECTROCATALYST; OXYGEN REDUCTION; NANOWIRE ARRAYS; ALKALINE MEDIA; EFFICIENT; CATALYSTS; CARBON; NANOPARTICLES; CATHODE; WATER;
D O I：
10.1021/acssuschemeng.8b00187
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal phosphides are promising efficient non-Pt electrocatalysts for hydrogen evolution reaction (HER). Herein, we report a simple strategy to controllably synthesize pure RuP and RuP2 and evaluate their HER performances in all pH range. Different from other transition metal phosphides, the HER performance of the RuP, in all pH range obviously improves as the phosphorus content decreases. By systematic research, it has been found that the RuP-475 with more Ru had much better conductivity and more catalytically active sites than the P rich RuP2-550. In addition, the RuP-475 exhibits excellent HER performance with small overpotential at a current density of 10 mA cm(-2) (46, 47, 22 mV in pH 0, 7, and 14, respectively).
引用
收藏
页码：6388 / 6394
页数：13
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