One-dimensional europium(III) coordination polymer based on 3-pyridylacrylic acid

被引：7
|
作者：
Liu, YJ
Xiong, RG [1 ]
You, XZ
Che, CM
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 15期
关键词：
europium; coordination polymer; fluorescent; hydrothermal synthesis; metal-organic framework;
D O I：
10.1002/zaac.200400144
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Under hydrothermal conditions, the reaction of racemic 3-pyridyl-3-aminopropionic acid (rac-HPAPA) with Eu(ClO4)(3)(.) 6H(2)O affords a l-D chain complex, [Eu(3-PYA)(3)(H2O)](n) (1) (3-PYA=3-pyridylacrylate), which represents an example of neutral l-D coordination polymeric material based on 3-HPYA (HPYA= pyridylacrylic acid) ligand with strong red fluorescent emission in the solid state.
引用
收藏
页码：2761 / 2764
页数：4
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