The synthesis and structure of P-C-P bridged ferrocene

被引：0

作者：

Shevchenko, I

Shakhnin, D

Zhang, HM

Lattman, M

Röschenthaler, GV

机构：

[1] Inst Bioorgan Chem, UA-02094 Kiev, Ukraine

[2] So Methodist Univ, Dept Chem, Dallas, TX 75275 USA

[3] Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 06期

关键词：

sandwich complexes; phosphane ligands; asymmetry; bridging ligands;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dilithioferrocene 12 with methylene-bis (dialkylaminochlorophosphanes) 13a,b (a = CH3, b = C2H5) leads to the formation of compounds 14a,b in which the two cyclopentadiene rings are bridged by a P-C-P chain. Because of the cyclic structure, cis- and trans-isomerism is expected. The cis- and trans-isomers of the sulfur derivative 16b have been separated by column chromatography. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：1169 / 1174

页数：6

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