STRUCTURE AND PROPERTIES OF POLYETHYLENE TEREPHTHALATE TREATED BY SUPERCRITICAL CO2

被引：3

作者：

Gao, Shi-Hui ^{[1
,2
]}

Han, Yi-Tong ^{[2
]}

Li, Fei-Xia ^{[2
]}

Yan, Jun ^{[2
]}

Lu, Yan-Hua ^{[3
]}

Zheng, Huan-Da ^{[2
]}

机构：

[1] Liaoning Vocat Coll Light Ind, Dalian, Liaoning, Peoples R China

[2] Dalian Polytech Univ, Liaoning Prov Key Lab Ecol Text, Dalian, Liaoning, Peoples R China

[3] Eastern Liaoning Univ, Liaoning Prov Key Lab Funct Text Mat, Dandong, Liaoning, Peoples R China

来源：

THERMAL SCIENCE | 2018年 / 22卷 / 04期

基金：

中国博士后科学基金;

关键词：

supercritical CO2; polyethylene terephthalate; treatment; shrinking dynamics equation; structure and properties; CARBON-DIOXIDE;

D O I：

10.2298/TSCI1804645G

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Structure and properties of polyethylene terephthalate were characterized by SAM Fourier transform infrared spectrometry, X-ray diffraction, and thermal analysis to evaluate the effect of supercritical CO2 on the structural behavior. The dynamic shrinking behavior of polyethylene terephthalate was analyzed using the Kelvin-Voigt model. The results indicated that uneven and significantly different surface of the polyethylene terephthalate fiber was displayed since the spinning oil and other additives added in spinning process were rinsed in supercritical CO2. The slight shifts for the characteristic bands of polyethylene terephthalate in Fourier transform infrared spectrometry were observed due to some re-arrangements and re-crystallizations of the molecule chains after supercritical CO2 treatment. Simultaneously, the crystallinities and the fastest thermal decomposition temperatures of polyethylene terephthalate were improved slightly from 80 degrees C to 120 degrees C in supercritical CO2. Furthermore, the shrinkage of the treated polyethylene terephthalate samples was increased gradually from 2.73% to 3.35% with the temperature raising.

引用

页码：1645 / 1650

页数：6

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