Regio- and Stereocontrol in Rhenium-Catalyzed Transposition of Allylic Alcohols

被引：77
|
作者：
Herrmann, Aaron T. [1 ]
Saito, Tatsuo [1 ]
Stivala, Craig E. [1 ]
Tom, Janine [1 ]
Zakarian, Armen [1 ]
机构：
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 17期
基金：
日本学术振兴会;
关键词：
METAL OXO COMPLEXES; MOLYBDENUM COMPLEXES; SILYL ETHERS; ISOMERIZATION; 1,3-ISOMERIZATION;
D O I：
10.1021/ja101673v
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis.
引用
收藏
页码：5962 / +
页数：3
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