A convenient synthesis of 1,2,3-triazole with glyoxal

被引：0
|
作者：
Harada, K [1 ]
Oda, M [1 ]
Matsushita, A [1 ]
Shirai, M [1 ]
机构：
[1] UBE Ind Ltd, Ube Res Lab, Ube, Yamaguchi 755, Japan
来源：
SYNLETT | 1998年 / 04期
关键词：
1,2,3-triazole; glyoxal; glyoxal mono-hydrazone mono-oxime; 2-acetyl-1,2,3-triazole;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new synthetic method of 1,2,3-triazole from glyoxal monohydrazone mono-oxime (1a) has been developed. 1a obtained by the thermal disproportionation of glyoxal bis-hydrazone (1b) and glyoxime (1c) was treated with acetic anhydride to give 2-acetyl-1,2,3-triazole, following alcoholysis gave 1,2,3-triazole in high yield.
引用
收藏
页码：431 / +
页数：4
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