Spontaneous symmetry breaking during interrupted crystallization of an axially chiral amino acid derivative

被引：12
|
作者：
Sephton, Mark A. [1 ]
Emerson, Christopher R. [1 ]
Zakharov, Lev N. [1 ]
Blakemore, Paul R. [1 ]
机构：
[1] Oregon State Univ, Dept Chem, Corvallis, OR 97331 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 12期
基金：
美国国家科学基金会;
关键词：
RACEMIC 1,1'-BINAPHTHYL; SPONTANEOUS RESOLUTION; CRYSTAL PHASE; SOLID-STATE; AUTOCATALYSIS; GENERATION; CATALYSTS; COMPLEX; MELT;
D O I：
10.1039/b922028c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High net enantiomeric excess was observed for crystal collections obtained by crystallization of the TFA salt of a configurationally stable yet racemic axially chiral amidoamine in EtOH solution with or without stirring (up to >99% ee at <= 15% crystallization).
引用
收藏
页码：2094 / 2096
页数：3
相关论文
共 50 条
  • [21] SPONTANEOUS SYMMETRY BREAKING FOR CHIRAL SCALAR SUPERFIELDS
    ORAIFEARTAIGH, L
    NUCLEAR PHYSICS B, 1975, 96 (02) : 331 - 352
  • [22] Spontaneous chiral symmetry breaking by hydromagnetic buoyancy
    Chatterjee, Piyali
    Mitra, Dhrubaditya
    Brandenburg, Axel
    Rheinhardt, Matthias
    PHYSICAL REVIEW E, 2011, 84 (02):
  • [23] Spontaneous chiral symmetry breaking in the Tayler instability
    Del Sordo, Fabio
    Bonanno, Alfio
    Brandenburg, Axel
    Mitra, Dhrubaditya
    COMPARATIVE MAGNETIC MINIMA: CHARACTERIZING QUIET TIMES IN THE SUN AND STARS, 2012, (286): : 65 - +
  • [24] Spontaneous chiral symmetry breaking in the NJL model
    Physics Reports, 265 (06):
  • [25] Spontaneous chiral symmetry breaking in liquid crystals
    Kats, E. I.
    LOW TEMPERATURE PHYSICS, 2017, 43 (01) : 5 - 7
  • [26] SPONTANEOUS BREAKING OF CHIRAL SYMMETRY FOR CONFINING POTENTIALS
    LEYAOUANC, A
    OLIVER, L
    PENE, O
    RAYNAL, JC
    PHYSICAL REVIEW D, 1984, 29 (06): : 1233 - 1257
  • [27] Spontaneous Chiral Symmetry Breaking for Finite Systems
    Boscheto, Emerson
    Lopez-Castillo, Alejandro
    CHEMPHYSCHEM, 2015, 16 (17) : 3728 - 3735
  • [28] SPONTANEOUS BREAKING OF CHIRAL SYMMETRY IN QUANTUM CHROMODYNAMICS
    NACHTMANN, O
    WETZEL, W
    PHYSICS LETTERS B, 1979, 81 (02) : 211 - 214
  • [29] Relativistic hydrodynamics with spontaneous chiral symmetry breaking
    Zhang, S
    Wang, F
    INTERNATIONAL JOURNAL OF MODERN PHYSICS E-NUCLEAR PHYSICS, 2003, 12 (05) : 675 - 681
  • [30] Spontaneous chiral symmetry breaking in bilayer graphene
    Zhang, Fan
    SYNTHETIC METALS, 2015, 210 : 9 - 18
12345