Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand

被引：25
|
作者：
Burrows, Andrew D. [1 ]
Frost, Christopher G. [1 ]
Mahon, Mary F. [1 ]
Raithby, Paul R. [1 ]
Richardson, Christopher [1 ,2 ]
Stevenson, Anna J. [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 28期
基金：
英国工程与自然科学研究理事会;
关键词：
METAL-ORGANIC FRAMEWORK; SINGLE-CRYSTAL TRANSFORMATION; GAS-ADSORPTION; POLYMER; CONSTRUCTION; EXCHANGE; BONDS; ANION;
D O I：
10.1039/c0cc00826e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of silver(I) perchlorate with the semi-rigid ligand 1,4-bis((3,5-dimethylisoxazol-4-yl)methyl) benzene (bisox) in methanol gives a triply-interpenetrated sheet structure, but a structure containing both interpenetrated sheets and Ag(2)(bisox)(3) cages is formed on recrystallisation from acetonitrile-diethyl ether. Rearrangement of the cages into sheets occurs on heating under vacuum, a process which involves a solid state change in conformation of the bisox ligands.
引用
收藏
页码：5064 / 5066
页数：3
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