Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand

被引：25

作者：

Burrows, Andrew D. ^{[1
]}

Frost, Christopher G. ^{[1
]}

Mahon, Mary F. ^{[1
]}

Raithby, Paul R. ^{[1
]}

Richardson, Christopher ^{[1
,2
]}

Stevenson, Anna J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Wollongong, Sch Chem, Wollongong, NSW 2522, Australia

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 28期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORK; SINGLE-CRYSTAL TRANSFORMATION; GAS-ADSORPTION; POLYMER; CONSTRUCTION; EXCHANGE; BONDS; ANION;

D O I：

10.1039/c0cc00826e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of silver(I) perchlorate with the semi-rigid ligand 1,4-bis((3,5-dimethylisoxazol-4-yl)methyl) benzene (bisox) in methanol gives a triply-interpenetrated sheet structure, but a structure containing both interpenetrated sheets and Ag(2)(bisox)(3) cages is formed on recrystallisation from acetonitrile-diethyl ether. Rearrangement of the cages into sheets occurs on heating under vacuum, a process which involves a solid state change in conformation of the bisox ligands.

引用

页码：5064 / 5066

页数：3

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