Syntheses, Structures and Thermal Stabilities of Three Co(II) Complexes Constructed from 3,5-Bis(4-pyridyl)-1,2,4-triazolyl

被引：0
|
作者：
Zhang You [1 ]
Zhao Can [1 ]
Wen Yi-Hang [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 30卷 / 11期
关键词：
3,5-bis(4-pyridyl)-1,2,4-triazolyl; coordination polymers; crystal structure; hydrogen bonds; pi-pi stacking; TGA property; PI-PI INTERACTIONS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; COBALT(II); PHOTOLUMINESCENCE; CHEMISTRY; TOPOLOGY;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three Co(II) complexes constructed from 3,5-bis(4-pyridyl)-1,2,4-triazolyl (Hbpt), namely [Co(Hbpt)(2)(HCOO)(2)(H2O)(2)](n)center dot 4nH(2)O (1), [Co(Hbpt)(2)(HCOO)(2)(H2O)(2)](n) (2) and [Co(bpt)(2)(H2O)(4)](n) center dot 2nH(2)O (3), have been hydrothermally synthesized and structurally characterized by IR spectroscopy and single crystal X-ray diffraction. The X-ray crystallographic analyses show that all of them present three-dimensional supramolecular frameworks in which crystal configurations are linked by pi-pi stacking interactions and strong intermolecular hydrogen-bonding interactions. In addition, the thermogravimetric analyses (TGA) for complexes 1 and 3 are also discussed. CCDC: 1001364, 1; 1001365, 2; 1001366, 3.
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页码：2645 / 2652
页数：8
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