Ni@C Microspheres as Efficient catalyst for Urea Electro-oxidation

被引:2
|
作者
Xu, Ran [1 ]
Huang, Jingyi [1 ]
Zhou, Yuming [1 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Jiangsu Optoelect Funct Mat & Engn Lab, Nanjing 211189, Peoples R China
来源
关键词
Ni@C microspheres; Ni-btc microspheres; Electro-oxidation; Urea; 3-DIMENSIONAL NICKEL FRAMEWORK; ELECTROCATALYTIC OXIDATION; ELECTROCHEMICAL DECOMPOSITION; HYDROXIDE NANOSHEETS; ANODE; GRAPHENE; ARRAYS; FOAM;
D O I
10.20964/2021.03.60
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Urea is able to be used as a useful fuel in the direct urea fuel cell. Novel structure and morphology is essential to improve the catalytic performance of catalysts for urea electro-oxidation. Preparation of Ni@C microspheres with Ni-btc (btc=benzene-1,3,5-tricarboxylate) microspheres as precursor was developed herein. These Ni@C microspheres are modified to the glassy carbon electrode and the electrocatalytic performance of Ni@C microspheres for urea electro-oxidation is investigated in an alkaline solution. Experimental results showed that Ni@C microspheres have excellent urea electro-oxidation performance which attributes to the electrocatalytic activity of Ni and high electrical conductivity of C in the Ni@C microspheres.
引用
收藏
页码:1 / 13
页数:13
相关论文
共 50 条
  • [31] MagnetoElectroCatalysis: A new approach for urea electro-oxidation reaction on nickel-iron oxide catalyst
    Rodrigues, Eduardo M.
    Fernandes, Caio Machado
    Alves, Odivaldo C.
    Santos, Evelyn C. S.
    Garcia, Flavio
    Xing, Yutao
    Ponzio, Eduardo A.
    Silva, Julio Cesar M.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 51 : 1460 - 1470
  • [32] Nickel nanowires as effective catalysts for urea electro-oxidation
    Yan, Wei
    Wang, Dan
    Diaz, Luis A.
    Botte, Gerardine G.
    ELECTROCHIMICA ACTA, 2014, 134 : 266 - 271
  • [33] Ni/C-CeO2 with Different Morphologies of CeO2 Towards Urea Electro-Oxidation Reaction
    Mendes Tanabe, Nassara Barbara
    Barbosa, Joseane Ribeiro
    Checca, Noemi Raquel
    Rodrigues, Thenner Silva
    Silva, Felipe Anchieta
    Alves, Odivaldo Cambraia
    Martins da Silva, Julio Cesar
    REVISTA VIRTUAL DE QUIMICA, 2020, 12 (06) : 1411 - 1422
  • [34] Electroless Ni–P coated on graphite as catalyst for the electro-oxidation of dextrose in alkali solution
    G. Veera Babu
    M. Palaniappa
    M. Jayalakshmi
    K. Balasubramanian
    Journal of Solid State Electrochemistry, 2007, 11 : 1705 - 1712
  • [35] Investigation of Pt/WC/C catalyst for methanol electro-oxidation and oxygen electro-reduction
    Jeon, Min Ku
    Lee, Ki Rak
    Lee, Won Su
    Daimon, Hideo
    Nakahara, Akemi
    Woo, Seong Ihl
    JOURNAL OF POWER SOURCES, 2008, 185 (02) : 927 - 931
  • [36] Free-standing Ni-Co alloy nanowire arrays: Efficient and robust catalysts toward urea electro-oxidation
    Gao, Xuesen
    Wang, Yining
    Li, Wen
    Li, Fei
    Arandiyan, Hamidreza
    Sun, Hongyu
    Chen, Yan
    ELECTROCHIMICA ACTA, 2018, 283 : 1277 - 1283
  • [37] Catalyst Based on Pt, Sn and Ni: Effect of Carbon Functionalization on Ethanol Electro-Oxidation
    Correa, Patricia dos Santos
    da Silva, Elen Leal
    de Sa, Stephanie Cardoso
    Radtke, Claudio
    Rieder, Ester Schmidt
    Malfatti, Celia de Fraga
    2012 12TH IEEE CONFERENCE ON NANOTECHNOLOGY (IEEE-NANO), 2012,
  • [38] Nitrogen-doped graphene/tungsten oxide microspheres as an electro-catalyst support for formic acid electro-oxidation
    Zhou, Yang
    Li, Chen
    Fu, Junxiang
    Yu, Changlin
    Hu, Xian-Chao
    RSC ADVANCES, 2016, 6 (95): : 92852 - 92856
  • [39] In-situ generated Ni(OH)2 on chemically activated spent catalyst sustains urea electro-oxidation in extensive alkaline conditions
    Alex, Chandraraj
    Kovilakath, Muhammed Safeer Naduvil
    Sathiskumar, Chinnusamy
    Tayal, Akhil
    Meesala, Lavanya
    Kumar, Pramod
    John, Neena S.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 59 : 390 - 399
  • [40] Recent Advances in the Electro-Oxidation of Urea for Direct Urea Fuel Cell and Urea Electrolysis
    Ye, Ke
    Wang, Gang
    Cao, Dianxue
    Wang, Guoxiong
    TOPICS IN CURRENT CHEMISTRY, 2018, 376 (06)