Polyaniline decorated honeycomb-patterned pores: Use of a reactive vapor in breath figure method

被引：19
|
作者：
Male, Umashankar [1 ]
Shin, Bo Kyoung [1 ]
Huh, Do Sung [1 ]
机构：
[1] Inje Univ, Ctr Nanomfg, Dept Chem & Nanosci & Engn, Gimhae City 621749, Gyeongsangnam D, South Korea
来源：
POLYMER | 2017年 / 121卷
基金：
新加坡国家研究基金会;
关键词：
Polyaniline; Breath figure method; Interfacial polymerization; Pore-decoration; Patterned porous films; POROUS FILMS; INTERFACIAL POLYMERIZATION; FABRICATION; COMPOSITES; MORPHOLOGY; TEMPLATE; ARRAYS;
D O I：
10.1016/j.polymer.2017.06.021
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new strategy is proposed to obtain pore functionalized honeycomb-patterned porous films by in-situ polymerization during breath figure process. The polystyrene with benzoyl peroxide mixture in chloroform was casted under reactive vapor conditions, generated by pumping air through aqueous aniline hydrochloride solution. The resulting films showed honeycomb patterned porous morphology with polyaniline functionalized pores. The formation of polyaniline was confirmed from color, conductivity, and UV-Visible studies. The strategy can be extended to obtain various pore functionalized films by choosing one reactant in polymer solution and other in humid vapors. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：149 / 154
页数：6
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