Fabrication of honeycomb-patterned polyalkylcyanoacrylate films from monomer solution by breath figures method

被引：30

作者：

Li, Xiaofeng ^{[1
,3
]}

Wang, Yang ^{[2
]}

Zhang, Liang ^{[1
,3
]}

Tan, Shuaixia ^{[1
]}

Yu, Xiaolan ^{[1
,3
]}

Zhao, Ning ^{[1
]}

Chen, Guoqiang ^{[2
]}

Xu, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China

[2] Tsinghua Univ, Sch Life Sci, Beijing 100084, Peoples R China

[3] Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2010年 / 350卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Poly(ethyl alpha-cyanoacrylate); Breath figures; Honeycomb-patterned; Monomer solution; POROUS POLYMER-FILMS; CHEMICAL-VAPOR-DEPOSITION; 2-CYANOACRYLATE POLYMERS; ALKYL CYANOACRYLATES; SELF-ORGANIZATION; BOTTOM-UP; WATER; LITHOGRAPHY; GROWTH; CYTOTOXICITY;

D O I：

10.1016/j.jcis.2010.06.046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Honeycomb-patterned polyalkylcyanoacrylate (PACA) films were prepared from the chloroform solutions of alkylcyanoacrylate (ACA) by breath figures (BFs) method. Condensed water droplets on the solution surface acted not only as templates to endow the ordered structure but also as initiators to trigger the polymerization of ACA. After the polymerization started, the in situ formed polymer chains self-assembled around the water droplets, structuring PACA film with a hexagonal arrangement of holes. This was the first time that polymerization was introduced to breath figures method. The formation mechanism and the influencing factors, including substrates, relative humidity, and solution concentrations were investigated. Hela cells were cultured on both flat and honeycomb-like PACA films to investigate their application as biomaterials. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：253 / 259

页数：7

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