Azobenzene modified metal-organic framework: For solar energy storage

被引：2
|
作者：
Li, Chen [1 ]
Zhang, Zhuo [1 ]
Zhong, Tianyuan [1 ]
Wang, Guang [1 ]
机构：
[1] Univ Jilin Prov, Northeast Normal Univ, Fac Chem, Key Lab Nanobiosensing & Nanobioanalysis, Changchun 130024, Peoples R China
来源：
JOURNAL OF ENERGY STORAGE | 2022年 / 52卷
基金：
中国国家自然科学基金;
关键词：
Azobenzene; Metal-organic framework; Photochromism; Solar energy storage; Application; CATALYSTS; PHOTOSWITCHES; EFFICIENT; DENSITY;
D O I：
10.1016/j.est.2022.104971
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
A novel photochromic azo-grafted metal-organic framework (MOF), ZIF-90-AAT, was synthesized and characterized. ZIF-90-AAT not only retains the three-dimensional porous structure of ZIF-90 and high thermal stability, but also has sufficient free space for the isomerization reaction of azobenzene and photo-energy storage ability. ZIF-90-AAT displayed excellent reversible photochromic performance and can release photo-energy absorbed during the isomerization process. The result of differential scanning calorimetry (DSC) indicated that the energy storage density of ZIF-90-AAT is 5.796 J/g. In addition, ZIF-90-AAT also has the ability to melt broken ice during the isomerization-back process. This work demonstrated that MOFs can be used in the energy storage and expanded the application range of MOF materials.
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页数：7
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